03 May Epoxymethyl di(m)ethyl phosphonate
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Epoxymethyl di(m)ethyl phosphonate (SP-3-15-003 & SP-3-15-006) are small reactive building-blocks that could be involved in both organic and polymerization reactions. Indeed, the epoxy group can be used in ring opening reactions with several nucleophilic precursors to access to β-Hydroxyphosphonates with different properties and activities. For example, these reactants are used in the synthesis of nucleoside analogs [1] or phosphonated polyols [2]. As monomers, SP-3-15-003 and SP-3-15-006 can react with epoxy resins and hardeners. In that case, phosphonate groups are inserted into the network conferring flame retardant properties to the resulting material.[3]
References
[1] M. Ganesan & K. M. Muraleedharan, Synthesis of β-Hydroxyphosphonate and 1,2-Dihydroxy Acyclic Nucleoside Analogs via 1,3-Dipolar Cycloaddition Strategy, Nucleosides, Nucleotides & Nucleic Acids, 29:2, 91-96, (2010) >
[2] B. Boutevin, and al., SYNTHESIS OF POLYOLS BEARING PHOSPHONATE GROUPS. PART II: EPOXIDES USED AS STARTING MATERIALS, Phosphorus, Sulfur, and Silicon and the Related Elements, 161:1, 9-27, (2000) >
[3] Fire retardant functionalized polyol by phosphonate monomer insertion, Polymer International (2015), 64(12), 1706-1714, (2015) >
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