06 Dec Synthesis and monomer reactivity ratios of ethyl α-acetoxyacrylate and acrylic acid copolymers Back to Sci. Publications

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AUTHORS

C. Loubat, D. Batt-Coutrot, B. Guyot, J-J. Robin, B. Boutevin

JOURNAL

Polymer International, 54, 11, 1557-1563

DATE

01st August 2005

PRODUCTS

SP-40-005 >

ABSTRACT

The synthesis of ethyl α-acetoxyacrylate (EAA) and the study of its radical polymerization is described. We report the monomer reactivity ratios for copolymers of EAA and acrylic acid (AA) using three different methods: the Jaacks, the Macret and the Fineman–Ross methods. Copolymers were obtained by free radical polymerization initiated by 2,2′-azobisisobutyronitrile in acetonitrile solutions and were analyzed by NMR and HPLC. The HPLC analysis was used to determine the molar fractions of EAA and AA in the copolymers. The reactivity ratios were estimated to be close to 1 for each monomer. Thus, copolymers of poly(acrylic acid) bearing some biodegradable units of EAA in the chain were subsequently prepared. The study of the hydrolysis of these units shows that only basic conditions were efficient to lead to hydrolyzed monomer units. Copyright © 2005 Society of Chemical Industry